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  • 2020/10/09 Shunhao moulds factory
    Shunhao moulds factory

    Shunhao moulds factory can make molds: 1. Melamine crockery moulds 2. Urea crockery moulds 3. Glossy melamine moulds 4. Matt finished melamine moulds ...

  • 2020-04-01 China Government interviewed with Shunhao
    China Government interviewed with Shunhao

    Shunhao factory has been serving the machines and molds to melamine tableware factories, urea tableware factories, UF toilet seat and cover factories ...

  • 2020/04/08 Rice husk tableware
    Rice husk tableware

    Rice husk tableware Introduction: Rice husk tableware is to regenerate this discarded rice husk into natural, healthy and free of any harmful chemical...

  • 2020/04/05 Rationally view the harm of melamine tableware
    Rationally view the harm of melamine tableware

    Rationally view the harm of melamine tableware 1) What is melamine tableware Melamine tableware is made from melamine powder (known in the industry as...

  • 2020/04/05 Precautions and cleaning of melamine tableware
    Precautions and cleaning of melamine tableware

    Precautions and cleaning of melamine tableware 1. Main ingredients of melamine tableware raw materials: 100% melamine (domestically called A5 material...

  • 2020/04/05 The advantages and disadvantages of melamine tableware
    The advantages and disadvantages of melamine tableware

    The advantages and disadvantages of melamine tableware In daily life, there are many meals used. Tableware is divided into ceramic tableware, bone chi...

Production process can produce melamine
03 Jun 2019
1. urea and corn at 120 degrees, 1.5MPa pressure can produce melamine it?

According to the test of China Agricultural University determined not to produce melamine in the production of gelatinized starch urea. From the technical point of view, the conditions for the production of melamine is high temperature, high pressure, low pressure method also need the catalyst to produce melamine. At present, urea is mainly used in the world to produce melamine, and urea can be divided into high pressure and low pressure according to the pressure. At present, the world's most advanced and highly competitive technologies include Japan's Nissan Law, Italy's Montedison Law, the Netherlands DSM Law and Germany's BASF Law. The first two kinds of high-pressure method, the temperature reached 380 degrees above the pressure of 8 MPa, the latter two were low pressure and atmospheric pressure method, the temperature reached 390 degrees, the pressure is 0.1-0.7 MPa.

The gelatinized starch urea production conditions are gelatinized starch processing temperature of 80-125 ℃, the pressure of 1.8-3.0MPa, the first is the temperature is not enough, there is no catalyst, and any of the above melamine production methods are different, do not have The chemical reaction conditions that produce melamine. Therefore, it is also proved from the production process that no melamine is produced during the production of gelatinized starch urea.

Melamine Tableware Die

2. If urea is added to milk, will melamine be produced in the process of milk powder production at 160 ° C?

This experiment for the "raw milk added urea resulting in the production of melamine in milk processing" argument for research, China Agricultural University in its pilot pasture to go through the test without melamine raw milk, milk samples four, one without urea Blank control group, the other three groups numbered as sample 1, sample 2 and sample 3, were added urea 1.030g, 5.150g and 10.30g, the concentration gradient settings were 1 ‰, 5 ‰ and 10 ‰. The experimental results show that no melamine was detected in the milk powder produced from the raw milk to which urea was added.

According to the composition of crude protein in milk, the milk itself contains urea urea nitrogen (1.3% -1.8% of the total protein in milk). If "the addition of urea in raw milk results in the production of melamine in milk powder processing," then , Milk powder produced at home and abroad may contain melamine. The reality is not the case.
Melamine Crockery Die
Technically speaking, the conditions for producing melamine are high temperature and high pressure, and some methods require a catalyst to produce melamine. The experiment simulated milk processing plant links, the production of milk powder. Set the inlet air temperature is 175 ℃, the air temperature is 70-75 ℃, the pressure is 120kpa. Temperature and the actual production of the same, the pressure is slightly smaller, because the pressure is mainly related to the height of the drying tower, because it is a small device, the height from the ground is small, can not set too high pressure, so in accordance with the production of milk powder temperature conditions Is 175 ° C, and in fact the temperature of the material (concentrated milk) does not exceed 90 ° C, otherwise it will cause protein denaturation), without catalyst, it is impossible to produce melamine.

From the cost point of view, the current general will not artificially added urea in raw milk, not to mention the smell of urea, the method of adding urea in milk is relatively old, the dairy plant has long been the corresponding adulteration identification technology to deal with.


2:Problems related to melamine products

What is melamine?

Melamine, commonly known as melamine, protein concentrate, is a pure white crystal, odorless organic compounds, is an important organic chemical raw materials. Soluble in methanol, formaldehyde and other organic solvents, slightly soluble in water, aqueous solution into a weak alkaline, with a variety of acids generated salt, only in strong acid and alkali hydrolysis.

Molecular Structure

2. The main purpose of melamine is what?

The main use of melamine is a versatile basic organic chemical intermediate, the primary use being as a raw material for the production of melamine formaldehyde resin (MF).

Melamine can also be used as flame retardants, water reducers, formaldehyde cleaners. The resin hardness than urea-formaldehyde resin, non-flammable, water, heat, aging resistance, arc resistance, chemical resistance, good insulation properties, gloss and mechanical strength, widely used in wood, plastic, paint, paper, textile , Leather, electrical, pharmaceutical and other industries.

3. Which products will produce melamine during use?

China's melamine production enterprises to use more semi-dry atmospheric pressure process, the method is to urea as the raw material below 0.1MPa, 390 ℃ or so, the silica gel as a catalyst for the synthesis of melamine and melamine in the desulfurizer crystallization, the crude dissolved , Filtered, made of finished products after crystallization.


The European Food Safety Authority (EFSA) in the EFSA-Q-2007-093 report concluded that the migration of melamine in packaging materials made from melamine-formaldehyde resins may contaminate the product. EFSA detected 0.54, 0.72, 1.42 and 2.2 mg / kg of melamine in coffee, orange juice, fermented milk and lemon juice beverages using liquid chromatography-mass spectrometry with a minimum detection limit of 0.05 mg / L. Experts believe These melamines migrate from the cup (the cup material is a melamine formaldehyde resin) into the beverage from heat and acid (95 ° C for 30 min).

Cyromazine Industrial synthesis will produce a very small amount of impurities as melamine. The main metabolite after use is melamine, which is mainly used as a veterinary drug in the control of flies and worms in livestock farms.
Melamine Tableware Die
Non-protein nitrogen, such as biuret, commonly used in ruminant feeds, contains cyanuric acid during its industrial synthesis.

According to the report (FAO / WHO, 2004), when drinking water uses sodium dichloroisocyanurate as a disinfectant (cyanuric acid analogues are produced due to rapid dechlorination of chlorine), experts believe that adults daily The amount of exposure to drinking water is 0.06 mg / kg body weight, 0.19 mg / kg body weight for children, and 0.28 mg / kg body weight per day for a bottle of milk.


3:Melamine and life-related health issues

1. What is the possibility of residual melamine in animal products that is ingested by animals (can melamine be transferred to meat, eggs and milk after ingestion by livestock and poultry)?

Melamine, which is ingested by animals, may remain in livestock products, meaning that melamine may be transferred to meat, eggs and milk after ingestion by livestock and poultry. However, the specific residual rate is affected by many factors, such as the content of melamine in the feed, the type of animal, the type of diet, the environment and the physiological condition of the animal.

2. Melamine on the human body what harm?
Melamine is currently considered mild and has a median lethal dose greater than 3 g / kg body weight. Long-term intake of melamine in animals can cause reproductive, urinary tract damage, bladder, kidney stones, and can further induce bladder cancer. In general, long-term consumption of renal dysfunction can lead to kidney failure, kidney stones. Due to the mature kidney function of adults and the detoxification function of the body, the melamine in food has little effect on adults and generally excretes in vitro. However, infants are greatly affected, and in severe cases, renal failure leads to death.

3. The body's tolerance to melamine how?
Melamine is a low toxicity chemical raw materials. Animal experiments show that its metabolism in the body quickly and will not survive, mainly affects the urinary system.

There is a significant dose-response relationship between melamine dose and clinical disease. The maximum tolerated melamine in infants is 15 milligrams per kilogram of powdered milk (based on experimental data from rodents). An expert assessment of the risk of contaminated infant formula shows, for example, an infant weighing 7 kg, assuming a daily intake of 150 grams of milk powder and a safe threshold of 15 mg / kg milk powder. According to the US Food and Drug Administration's recommended data, daily intake of melamine 0.63 mg / kg body weight daily.

4. Furniture and paper processing technology is also used to melamine, they will not evaporate into the air through the body?

The most extensive use of melamine is the production of organic chemical intermediates, can be used as flame retardants, water reducers, formaldehyde cleaners. Can also be used as raw material for the production of melamine formaldehyde resin (MF), but also mixed with other raw materials to produce a fabric finishing agent, leather tanning agent, polishing agent and water repellent agent, rubber binder, efficient cement superplasticizer (Naphthalene as raw material), steel nitriding agent.
In general, melamine has the characteristics of non-flammability, water resistance, heat resistance, aging resistance, arc resistance, chemical resistance, good insulation properties, gloss and mechanical strength. Very stable and will not evaporate through the air.

Melamine Crockery Mould
However, the harm of free isocyanate (TDI) emitted from urethane paint or polyurethane paint foam to human body needs further study in medicine. Although some people think it is a carcinogen, but have not yet seen sufficient evidence of animal experiments. However, according to the construction workers at the working site of the body reaction, you can initially believe that isocyanates have a greater impact on human health, some people feel dizzy, headache, nausea, shortness of breath, and even very few people smell the smell immediately vomiting Serious will immediately unconscious. Therefore, the national standard of polyurethane coatings in the free isocyanate content has made strict restrictions.

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